Use a gas mask as a preventive measure, if there is any risk of chlorine dioxide in the air. Direct contact with chlorine dioxide causes eye and skin irritation and may cause burns. Chlorine dioxide gas will be released in the event of a spill. Chlorine dioxide cannot be stored for too long, because it slowly dissociates into chlorine and oxygen. Chlorine dioxide gas please note that the layout and pagination of this pdf file are not necessarily identical to those of the pinted cicad first draft prepared by dr stuart dobson, institute of terrestrial ecology, huntingdon, united kingdom, and mr richard cary. Chlorine vapors can cause irritation, burning and blisters. Sodium chlorite is converted to chlorine dioxide through a chlorine dioxide generator and applied as a dilute solution. Reason for citation chlorine dioxide is on the hazardous substance list.
Box 858 ashtabula, oh 44004 440 9975221 chlorine liquid. Preparation of technicalgrade chlorine dioxide solutions. Protective equipment and precautions for firefighters. Subchronic toxicity of chlorine dioxide and related compounds in drinking water in the nonhuman primate. The clo 2 disinfecting molecule produced by cidoxtm is not sensitive to high ph environments, and has more than 2. Please note that the layout and pagination of this pdf file are not. Liquid chlorine safety data sheet according to federal register vol. The available data suggest that chlorine dioxide and chlorite. It is unstable and highly reactive at concentrations above 10% in air, and is a strong oxidizing agent.
Sodium chlorite laboratory preparations of chlorine. There are many articles on this and other websites on the use of mms, miracle mineral supplement, activated sodium chlorite andor chlorine dioxide. Chlorine dioxide chlorine dioxide exists as a gas at normal temperatures and pressures and has the chemical formula clo 2 it is a highly effective, ecofriendly microbiocide that carries a number of important regulatory approvals from several international organisations including the us epa, fda and uk government for many of its uses. This chemical is normally handled as water solution, typically containing 1012 gl of chlorine dioxide. At high concentrations chlorine dioxide gas can be explosive, and may be fatal if inhaled. Chlorine dioxide is a molecule which is being suggested for use against infections and cancer which are associated with microbes. P4580 410 this document is only controlled while on the praxair, inc. Unusual fire or explosive hazards the sodium chlorite in dried purogene is a strong oxidizer, which supports combustion. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye.
Chlorine dioxide is quickly broken down into other chlorine derivatives such as chlorate, chlorite and chloride. It is used for a variety of antimicrobial uses, including the disinfection of drinking water. Groups at potentially high risk from chlorine dioxide treated water. Chlorine dioxide is a gas produced by activating sodium chlorite with an oxidizing agent or an acid source. Cdc niosh pocket guide to chemical hazards chlorine. Cdg solution 3000 liquid concentrate means that no onsite production equipment is needed. Gas mask, safety goggles and safety gloves are necessary when dealing with large. Prokure v ready to use solution page 1 of 9 safety data sheet this sds complies with reach 19072006 and 200158ec, ghs, osha 29cfr 1910.
Eyes exposure to chlorine gas may cause severe eye damage. May have synergistic effects in conjunction with chlorine, other chlorine oxides and chlorine fluorine compounds. Identification of the substance liquid chlorinecloro liquido cas number 7782505 alternative numbers e2002004 1. Drinking water requirements for chlorine residual analysis.
Chlorine dioxide, which may evolve from purogene solutions, isexplosive in the gaseous phase at concentrations greater than 10%. It is rarely stored as a gas, because it is explosive under pressure. If chlorine dioxide gas is produced, vent to atmosphere. Material safety data sheet sabre technical services, llc. Prokure v ready to use solution sds pantheon enterprises.
Accidental release measures leak or spill procedures. It is used to bleach wood pulp, textiles and oils, in processing flour, and for water purification. Chlorine safety data sheet p4580 this sds conforms to u. Since chlorine dioxide is an irritating oxidizer, always work in a wellventilated hood. Gaseous chlorine dioxide can only be handled diluted with air or other inert gas, when its. Reactivity chlorine dioxide gas is normally stable at concentrations up to 10% vv in air, but contact with oxidizable materials can cause decomposition at lower concentrations. Stabilised chlorine tablets 20g200g 9 physical and chemical properties 9. Use full faceshield and chemical safety goggles when there is potential for contact.
Safety data sheet chlorine dioxide gas page 3 of 5 synergistic materials. Chlorine dioxide gas please note that the layout and pagination of this pdf file are not necessarily identical to those of the pinted cicad first draft prepared by dr stuart dobson, institute of terrestrial ecology, huntingdon, united kingdom, and mr richard cary, health and safety executive, liverpool, united kingdom. High concentrations of chlorine dioxide may occur in air during manufacture. Envirox chlorine dioxide clo 2 generation system was designed with safety, reliability, and ease of use in mind. Safety data sheet page 4 of 12 interaction with other chemicals which enhance toxicity. Chlorine dioxide vapors are emitted when this product contacts acids, chlorine or bleach. Cdg solution 3000 liquid concentrate is eparegistered pure chlorine dioxide. Introduction chlorine dioxide clo2 is an effective disinfectant and an oxidant that is widely used in water treatment.
It is a reddish to yellowishgreen gas at room temperature that dissolves in water. Controlled clinical evaluations of chlorine dioxide. Safety data sheet 1 identification of the substance. Chlorine dioxide gas is usually produced onsite from sodium. Sabre s chlorine dioxide material safety data sheet with information from epa, osha, and other regulatory agencies. General comments about the safe use of chlorine dioxide. Material safety data sheet chlorine dioxide this msds is supplied by pureline treatment systems as a service to clients. Concise international chemical assessment document 37. Studies have shown that it produces as high as a 6log reduction. Material safety data sheet sabre technical services. Eye contact hold eye open and rinse slowly and gently with water for 15 20 minutes. Chlorine dioxide gas is very toxic, corrosive and poses a very serious inhalation hazard. General safety guidelines read msds guidelines of dutrion tablet first. It is commonly used to remove biofilm in irrigation systems and clogged emitters.
Section 1 chemical product and company identification pureline treatment systems 707 s. This includes melanoma, squamous cell carcinoma, and breast cancer. Chlorine dioxide clo2 is a chemical compound consisting of one chlorine atom and two oxygen atoms. Mixing with ammonia, acids, detergents, or organic matter will release chlorinated compounds, which are irritating to eyes, lungs, and mucus membranes. Diklor g chlorine dioxide sterilant precursor is a sporicidal decontaminant that inactivates bacillus anthracis spores on precleaned, hard, nonporous and porous surfaces at certain sites when used in accordance with all precautions and directions specified on the label and in this fumigation manual.
At ambient temperatures, chlorine dioxide is a reactive gas that is potentially explosively unstable at concentrations above 10% by. Additionally, chloride is the major in vivo degradation product for chlorine dioxide, chlorite, and chlorate. Show this safety data sheet to the doctor in attendance. Youbin zheng, siobhan dunets and diane cayanan university of guelph, guelph, ontario, canada background chlorine dioxide is a strong disinfectant that is 25 times more effective than chlorine gas and is effective at a wide ph range 410. Sulfur dioxide safety data sheet p4655 this sds conforms to u. Currently used in the usa and eu in dozens of industries and hundreds of applications. Chlorine dioxide cidoxtm how it works cidox tm range chlorine dioxide clo 2 is chemically dissimilar and acts differently to chlorine. Once absorbed, chlorine dioxide and chlorite are cleared from the blood at similar rates and are similarly distributed throughout the body abdelrahman et al. Chlorine dioxide use, benefits, and chemical safety facts.
Chlorine dioxide chlorine peroxide, clo 2 10049044 1. Fact sheet or material safety data sheet msds before handling chlorine dioxide in any form. At ambient temperatures, chlorine dioxide is a reactive gas that is potentially explosively unstable at concentrations above 10% by volume in air. Unsuitable extinguishing media do not use dry chemicals, carbon dioxide or halogenated extinguishing agents. Chlorine dioxide is a yellow to red gas with an irritating odor similar to chlorine. Bercz jp, jones l, garner l, murray d, ludwig da, boston j. Call a poison control center or doctor for treatment advice. For use as directed, on and around humans, pets, plants, food, water, materials and environment. Available in the healthcare and hospitality industry, this singleprecursor clo 2 generation system can help reduce risks due to waterborne pathogens. Chlorine dioxide solution in concentrations of between 0. Chlorine dioxide store chlorine dioxide safely removes.
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